Antioxidant activities and polyphenolic identification by UPLC-MS/MS of autoclaved brewers’ spent grain

Kütt Mary-Liis; Laaksonen Oskar; Föste Maike; Korzeniowska Małgorzata; Wojdyło Aneta; Yang Baoru; Naibaho Joncer
Antioxidant activities and polyphenolic identification by UPLC-MS/MS of autoclaved brewers’ spent grain

Kütt Mary-Liis
Laaksonen Oskar
Föste Maike
Korzeniowska Małgorzata
Wojdyło Aneta
Yang Baoru
Naibaho Joncer
Katso/Avaa
Lataukset: 

Academic Press
doi:10.1016/j.lwt.2022.113612
URI
https://www.sciencedirect.com/science/article/pii/S0023643822005473
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Julkaisun pysyvä osoite on:
https://urn.fi/URN:NBN:fi-fe2022081155071
Tiivistelmä

Autoclave treatment (AT) modified the dietary fiber composition of brewers' spent grain (BSG), impacting its techno-processing properties. However, its impact on antioxidant properties and stability of polyphenolic compounds remain unclear. This study aimed to evaluate the influence of AT on several antioxidant activities and polyphenolic composition. The results showed that AT increased ORAC (oxygen radical absorbance capacity), ABTS (2,2′-Azinobis-(3-ethylbenzthiazoline-6-sulfonic acid), and FRAP (ferric-reducing antioxidant power) value upto 7 folds compared to the untreated BSG. The lower temperature degraded the amount of flavan-3-ols and phenolic acids. However, AT at 110 °C and 130 °C upgraded the phenolic acids upto 4 and 11 folds respectively. Higher temperature also induced the formation of benzoic acid and (+)-catechin. UPLC-MS/MS identified several phenolic acids including syringic acid, benzoic acid, coumaric acid, ferulic acid and its derivatives, and flavan-3-ols such as (+)-catechin and (−)-epicatechin. In conclusion, AT improved the bioactivity of BSG, enhanced the amount of certains phenolic compounds and released the bioactive compounds from BSG matrices thus offering a higher benefit for industry to utilise autoclaved BSG.

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