Cobalt(III) complex with a redox non-innocent bis (o-aminophenol)

Tietueen suppeat tiedot
dc.contributor.authorLehtonen Ari
dc.contributor.authorSapkota Narhari
dc.contributor.authorPeuronen Anssi
dc.contributor.organizationfi=kemian laitos|en=Department of Chemistry|
dc.contributor.organizationfi=kestävän kehityksen materiaalien kemia|en=Materials Chemistry of Sustainable Development|
dc.contributor.organization-code1.2.246.10.2458963.20.27622076134
dc.contributor.organization-code1.2.246.10.2458963.20.58797367834
dc.converis.publication-id387182743
dc.converis.urlhttps://research.utu.fi/converis/portal/Publication/387182743
dc.date.accessioned2025-08-28T03:05:16Z
dc.date.available2025-08-28T03:05:16Z
dc.description.abstract<p>The redox non-innocent ligand bis(<em>o</em>-aminophenol) N,N '-bis(3,5-di-tertbutyl-2-hydroxy-phenyl)-1,2-phenyl-enediamine, H<sub>4</sub>L, reacts with CoCl<sub>2</sub>.6H<sub>2</sub>O in a methanol solution under aerobic conditions to form [Co(HL)<sub>2</sub>]. Both bis(<em>o</em>-aminophenol) ligands coordinate as tridentate and the ligand set can be described as a resonance structure of two partially oxidized ligands, while the formal oxidation state of the metal centre appears as + III. In this resonance structure, one ligand carries an odd electron, which makes the Co(III) complex paramagnetic.<br></p>
dc.identifier.eissn1879-0259
dc.identifier.jour-issn1387-7003
dc.identifier.olddbid210180
dc.identifier.oldhandle10024/193207
dc.identifier.urihttps://www.utupub.fi/handle/11111/50451
dc.identifier.urlhttps://www.sciencedirect.com/science/article/pii/S1387700323013163?via%3Dihub
dc.identifier.urnURN:NBN:fi-fe2025082792634
dc.language.isoen
dc.okm.affiliatedauthorLehtonen, Ari
dc.okm.affiliatedauthorSapkota, Narhari
dc.okm.affiliatedauthorPeuronen, Anssi
dc.okm.discipline116 Chemical sciencesen_GB
dc.okm.discipline116 Kemiafi_FI
dc.okm.internationalcopublicationnot an international co-publication
dc.okm.internationalityInternational publication
dc.okm.typeA1 ScientificArticle
dc.publisherELSEVIER
dc.publisher.countryNetherlandsen_GB
dc.publisher.countryAlankomaatfi_FI
dc.publisher.country-codeNL
dc.publisher.placeAMSTERDAM
dc.relation.articlenumber111704
dc.relation.doi10.1016/j.inoche.2023.111704
dc.relation.ispartofjournalInorganic Chemistry Communications
dc.relation.volume159
dc.source.identifierhttps://www.utupub.fi/handle/10024/193207
dc.titleCobalt(III) complex with a redox non-innocent bis (o-aminophenol)
dc.year.issued2024

Tiedostot

Näytetään 1 - 1 / 1
Name:
1-s2.0-S1387700323013163-main.pdf
Size:
707.79 KB
Format:
Adobe Portable Document Format
Lataa

Kokoelmat

Rinnakkaistallenteet