Oxidation of glucose and arabinose mixtures over Au/Al2O3

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dc.contributor.authorFranz Sebastian
dc.contributor.authorShcherban Nataliya D.
dc.contributor.authorSimakova Irina L.
dc.contributor.authorPeurla Markus
dc.contributor.authorEränen Kari
dc.contributor.authorWärnå Johan
dc.contributor.authorSalmi Tapio
dc.contributor.authorMurzin Dmitry Yu.
dc.contributor.organizationfi=biolääketieteen laitos|en=Institute of Biomedicine|
dc.contributor.organization-code1.2.246.10.2458963.20.77952289591
dc.converis.publication-id50964476
dc.converis.urlhttps://research.utu.fi/converis/portal/Publication/50964476
dc.date.accessioned2022-10-28T12:34:21Z
dc.date.available2022-10-28T12:34:21Z
dc.description.abstractOxidation of a mixture of glucose and arabinose over 1% Au deposited on alumina was investigated in a semi-batch reactor varying pH, temperature and partial pressure of oxygen. Elevation of the latter enhancing the rate induced also losses in selectivity to aldonic acids. A kinetic model representing the catalytic oxidation reactions of arabinose and glucose along with respective isomerization to fructose and ribulose was developed. Calculations based on the model were able to describe experimental data in a reliable way.
dc.format.pagerange59
dc.format.pagerange72
dc.identifier.eissn1878-5204
dc.identifier.jour-issn1878-5190
dc.identifier.olddbid177404
dc.identifier.oldhandle10024/160498
dc.identifier.urihttps://www.utupub.fi/handle/11111/33593
dc.identifier.urnURN:NBN:fi-fe2021042825244
dc.language.isoen
dc.okm.affiliatedauthorPeurla, Markus
dc.okm.discipline116 Chemical sciencesen_GB
dc.okm.discipline116 Kemiafi_FI
dc.okm.internationalcopublicationinternational co-publication
dc.okm.internationalityInternational publication
dc.okm.typeA1 ScientificArticle
dc.publisherSPRINGER
dc.publisher.countryNetherlandsen_GB
dc.publisher.countryAlankomaatfi_FI
dc.publisher.country-codeNL
dc.relation.doi10.1007/s11144-020-01901-w
dc.relation.ispartofjournalReaction Kinetics, Mechanisms and Catalysis
dc.relation.volume132
dc.source.identifierhttps://www.utupub.fi/handle/10024/160498
dc.titleOxidation of glucose and arabinose mixtures over Au/Al2O3
dc.year.issued2021

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