Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts

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dc.contributor.authorSalonen Pasi
dc.contributor.authorPeuronen Anssi
dc.contributor.authorLehtonen Ari
dc.contributor.organizationfi=kestävän kehityksen materiaalien kemia|en=Materials Chemistry of Sustainable Development|
dc.contributor.organization-code1.2.246.10.2458963.20.58797367834
dc.converis.publication-id27312788
dc.converis.urlhttps://research.utu.fi/converis/portal/Publication/27312788
dc.date.accessioned2022-10-28T13:04:26Z
dc.date.available2022-10-28T13:04:26Z
dc.description.abstract<p>Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO<sub>4</sub>·xH<sub>2</sub>O and ligand precursors in MeOH solutions. Isolated compounds were studied as <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/catechol-oxidase" title="Learn more about Catechol oxidase">catechol oxidase</a> models as well as catalysts for epoxidation and sulfoxidation reactions. All compounds can catalyse such oxidation reactions without notable structure-activity correlations. The <sup>51</sup>V NMR studies indicate that the complexes turn to the number of different species during the catalytic experiments.</p>
dc.format.pagerange165
dc.format.pagerange167
dc.identifier.eissn1879-0259
dc.identifier.jour-issn1387-7003
dc.identifier.olddbid179517
dc.identifier.oldhandle10024/162611
dc.identifier.urihttps://www.utupub.fi/handle/11111/37223
dc.identifier.urlhttps://www.sciencedirect.com/science/article/pii/S1387700317306925
dc.identifier.urnURN:NBN:fi-fe2021042717399
dc.language.isoen
dc.okm.affiliatedauthorSalonen, Pasi
dc.okm.affiliatedauthorLehtonen, Ari
dc.okm.affiliatedauthorPeuronen, Anssi
dc.okm.discipline116 Chemical sciencesen_GB
dc.okm.discipline216 Materials engineeringen_GB
dc.okm.discipline116 Kemiafi_FI
dc.okm.discipline216 Materiaalitekniikkafi_FI
dc.okm.internationalcopublicationnot an international co-publication
dc.okm.internationalityInternational publication
dc.okm.typeA1 ScientificArticle
dc.publisherElsevier B.V.
dc.publisher.countryNetherlandsen_GB
dc.publisher.countryAlankomaatfi_FI
dc.publisher.country-codeNL
dc.relation.doi10.1016/j.inoche.2017.10.017
dc.relation.ispartofjournalInorganic Chemistry Communications
dc.relation.volume86
dc.source.identifierhttps://www.utupub.fi/handle/10024/162611
dc.titleOxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts
dc.year.issued2017

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