Oxidovanadium(v) complexes with L-proline-based amino acid phenolates

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dc.contributor.authorSalonen P
dc.contributor.authorPeuronen A
dc.contributor.authorSinkkonen J
dc.contributor.authorLehtonen A
dc.contributor.organizationfi=analytiikkakeskus|en=Analytiikkakeskus|
dc.contributor.organizationfi=kestävän kehityksen materiaalien kemia|en=Materials Chemistry of Sustainable Development|
dc.contributor.organization-code1.2.246.10.2458963.20.58797367834
dc.contributor.organization-code2606304
dc.converis.publication-id39815004
dc.converis.urlhttps://research.utu.fi/converis/portal/Publication/39815004
dc.date.accessioned2022-10-27T11:59:07Z
dc.date.available2022-10-27T11:59:07Z
dc.description.abstractL-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1-4. These proligands react with vanadium precursors VO(acac)(2,) VOSO4 center dot 5H(2)O and VO(OPr)(3) in methanol to form the corresponding oxidoalkoxidovanadium(v) complexes 1-4. The complexes crystallize from methanol, and are octahedrally co-ordinated with a general formula [VO(L1-4)(OMe)(MeOH)]. In solution, however, they adopt several different conformations or isomeric structures depending on the solvent.
dc.format.pagerange108
dc.format.pagerange114
dc.identifier.eissn1873-3255
dc.identifier.jour-issn0020-1693
dc.identifier.olddbid173301
dc.identifier.oldhandle10024/156395
dc.identifier.urihttps://www.utupub.fi/handle/11111/31282
dc.identifier.urnURN:NBN:fi-fe2021042821609
dc.language.isoen
dc.okm.affiliatedauthorSalonen, Pasi
dc.okm.affiliatedauthorPeuronen, Anssi
dc.okm.affiliatedauthorSinkkonen, Jari
dc.okm.affiliatedauthorLehtonen, Ari
dc.okm.discipline116 Chemical sciencesen_GB
dc.okm.discipline216 Materials engineeringen_GB
dc.okm.discipline116 Kemiafi_FI
dc.okm.discipline216 Materiaalitekniikkafi_FI
dc.okm.internationalcopublicationnot an international co-publication
dc.okm.internationalityInternational publication
dc.okm.typeA1 ScientificArticle
dc.publisherELSEVIER SCIENCE SA
dc.relation.doi10.1016/j.ica.2019.02.011
dc.relation.ispartofjournalInorganica Chimica Acta
dc.relation.volume489
dc.source.identifierhttps://www.utupub.fi/handle/10024/156395
dc.titleOxidovanadium(v) complexes with L-proline-based amino acid phenolates
dc.year.issued2019

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