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Synthesis of an Azide- and Tetrazine-Functionalized [60]Fullerene and Its Controlled Decoration with Biomolecules
Gulumkar Vijay; Tähtinen Ville; Ali Aliaa; Rahkila Jani; Valle-Delgado Juan José; Äärelä Antti; Österberg Monika; Yliperttula Marjo; Virta Pasi<p>Bingel cyclopropanation between Buckminster fullerene and a heteroarmed malonate was utilized to produce a hexakis-functionalized C<sub>60</sub> core, with azide and tetrazine units. This orthogonally bifunctional ...